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Journal Articles

Current status of the high intensity pulsed spallation neutron source at J-PARC

Takada, Hiroshi

Plasma and Fusion Research (Internet), 13(Sp.1), p.2505013_1 - 2505013_8, 2018/03

The pulsed spallation neutron source of Japan Proton Accelerator Research Complex (J-PARC) has been supplying users with high intensity and sharp pulse cold neutrons using the moderators with following distinctive features; (1) 100% para-hydrogen for increasing pulse peak intensity with decreasing pulse tail, (2) cylindrical shape with 14 cm diam.$$times$$12 cm long for providing high intensity neutrons to wide neutron extraction angles of 50.8$$^{circ}$$, (3) neutron absorber made from Ag-In-Cd alloy to make pulse width narrower and pulse tails lower. Actually, it was measured at a low power operation that high neutron intensity of 4.5$$times$$10$$^{12}$$ n/cm$$^{2}$$/s/sr could be emitted from the coupled moderator surface for 1-MW operation, and a superior resolution of $$Delta$$d/d = 0.035% was achieved at a beamline (BL8) with a poisoned moderator, where d is the d-spacing of reflection. Towards the goal to achieve the target operation at 1-MW for 5000 h in a year, technical developments to mitigate cavitation damages on the target vessel with injecting gas micro-bubbles into mercury target and design improvement of target vessel structure to reducing welds and bolt connections as much as possible are under way.

Journal Articles

Implementation of a low-activation Au-In-Cd decoupler into the J-PARC 1 MW short pulsed spallation neutron source

Teshigawara, Makoto; Ikeda, Yujiro; Oi, Motoki; Harada, Masahide; Takada, Hiroshi; Kakishiro, Masanori*; Noguchi, Gaku*; Shimada, Tsubasa*; Seita, Kyoichi*; Murashima, Daisuke*; et al.

Nuclear Materials and Energy (Internet), 14, p.14 - 21, 2018/01

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

We developed an Au-In-Cd (AuIC) decoupler material to reduce induced radioactivity instead of Ag-In-Cd one, which has a cut off energy of 1eV. In order to implement it into an actual moderator-reflector assembly, a number of critical engineering issues need to be resolved with regard to large-sized bonding between AuIC and A5083 alloys by the hot isostatic pressing process. We investigated this process in terms of the surface conditions, sizes, and heat capacities of large AuIC alloys. We also show a successful implementation of an AuIC decoupler into a reflector assembly, resulting in a remarkable reduction of radioactivity by AuIC compared to AIC without sacrificing neutronic performance.

Journal Articles

Surface modifications of hydrogen storage alloy by heavy ion beams with keV to MeV irradiation energies

Abe, Hiroshi; Tokuhira, Shinnosuke*; Uchida, Hirohisa*; Oshima, Takeshi

Nuclear Instruments and Methods in Physics Research B, 365(Part A), p.214 - 217, 2015/12

no abstracts in English

Journal Articles

Mechanisms of oxygen reduction reactions for carbon alloy catalysts via first principles molecular dynamics

Ikeda, Takashi; Hou, Z.*; Chai, G.-L.*; Terakura, Kiyoyuki*

Hyomen Kagaku, 36(7), p.345 - 350, 2015/07

Carbon alloy catalysts (CACs) are one of promising candidates for platinum-substitute cathode catalysts for polymer electrolyte fuel cells. We have investigated possible mechanisms of oxygen reduction reactions (ORRs) for CACs via first-principles-based molecular dynamics simulations. In this contribution, we review possible ORRs at likely catalytic sites of CACs suggested from our simulations.

Journal Articles

Development of aluminum (Al5083)-clad ternary Ag-In-Cd alloy for JSNS decoupled moderator

Teshigawara, Makoto; Harada, Masahide; Saito, Shigeru; Oikawa, Kenichi; Maekawa, Fujio; Futakawa, Masatoshi; Kikuchi, Kenji; Kato, Takashi; Ikeda, Yujiro; Naoe, Takashi*; et al.

Journal of Nuclear Materials, 356(1-3), p.300 - 307, 2006/09

 Times Cited Count:9 Percentile:53.29(Materials Science, Multidisciplinary)

We adopted silver-indium-cadmium (Ag-In-Cd) alloy as a material of decoupler for decoupled moderator in JSNS. However, from the heat removal and corrosion protection points of view, the Ag-In-Cd alloy is needed to clad between Al alloys (Al5083). We attempted to obtain good bonding conditions for between Al5083 and ternary Ag-In-Cd alloys by HIPing tests. The good HIP condition was found for small test piece ($$Phi$$20mm). Though a hardened layer due to the formation of AlAg$$_{2}$$ was found in the bonding layer, the rupture strength of the bonding layer was more than 20 MPa, which was the calculated design stress. Bonding tests of a large size piece (200$$times$$200$$times$$30 mm$$^{3}$$), which simulated the real scale, were also performed according to the results of small size tests. The result also gave good bonding and enough required-mechanical-strength, however the rupture strength of the large size test was smaller than that of small one.

Journal Articles

Overview of design and R&D of test blankets in Japan

Enoeda, Mikio; Akiba, Masato; Tanaka, Satoru*; Shimizu, Akihiko*; Hasegawa, Akira*; Konishi, Satoshi*; Kimura, Akihiko*; Koyama, Akira*; Sagara, Akio*; Muroga, Takeo*

Fusion Engineering and Design, 81(1-7), p.415 - 424, 2006/02

 Times Cited Count:62 Percentile:96.39(Nuclear Science & Technology)

no abstracts in English

Journal Articles

Cladding technique for development of Ag-In-Cd decoupler

Teshigawara, Makoto; Harada, Masahide; Saito, Shigeru; Kikuchi, Kenji; Kogawa, Hiroyuki; Ikeda, Yujiro; Kawai, Masayoshi*; Kurishita, Hiroaki*; Konashi, Kenji*

Journal of Nuclear Materials, 343(1-3), p.154 - 162, 2005/08

 Times Cited Count:10 Percentile:56.65(Materials Science, Multidisciplinary)

For decoupled and poisoned moderator, a thermal neutron absorber, i.e., decoupler, is located around the moderator to give neutron beam with a short decay time. A B4C decoupler is already utilized, however, it is difficult to use in a MW class source because of He void swelling and local heating by (n,a) reaction. Therefore, a Ag-In-Cd (AIC) alloy which gives energy-dependence of macroscopic neutron cross section like that of B$$_{4}$$C was chosen. However, from heat removal and corrosion protection points of view, AIC is needed to bond between an Al alloy (A6061-T6), which is the structural material of a moderator. An AIC plate is divided into a Ag-In (15wt%) and Ag-Cd (35wt%) plate to extend the life time, shorten by burn up of Cd. We performed bonding tests by HIP (Hot Isostatic Pressing). We found out that a better HIP condition was holding at 803 K, 100 MPa for 1 h for small test pieces (f20mm). Though a hardened layer is found in the bonding layer, the rupture strength of the bonding layer is more than 20 MPa, which is less than that of the design stress.

Journal Articles

Distillation of cadmium from uranium-plutonium-cadmium alloy

Kato, Tetsuya*; Iizuka, Masatoshi*; Inoue, Tadashi*; Iwai, Takashi; Arai, Yasuo

Journal of Nuclear Materials, 340(2-3), p.259 - 265, 2005/04

 Times Cited Count:24 Percentile:81.08(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Characterization of rust layer formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich environment by Cl and Fe K-edge XANES measurements

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 46(2), p.329 - 336, 2005/02

 Times Cited Count:28 Percentile:80.32(Materials Science, Multidisciplinary)

Chloride in atmosphere considerably reduces the corrosion resistance of conventional weathering steel containing a small amount of Cr. Ni is an effective anticorrosive element for improving the corrosion resistance of steel in a Cl-rich environment. In order to clarify the structure of the protective rust layer of weathering steel, Cl and Fe K-edge X-ray absorption near edge structure (XANES) spectra of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys exposed to Cl-rich atmosphere were measured. The Fe K-XANES measurements enable the characterization of a mixture of iron oxides such as rust. The chemical composition of the rust was determined by performing pattern fitting of the measured spectra. All the rust is composed mainly of goethite, akagan$'e$ite, lepidocrocite and magnetite. Among these iron oxides, akagan$'e$ite in particular is the major component in the rust. Additionally, the amount of akagan$'e$ite in the rust of Fe-Ni alloy is much greater than that in rust of Fe-Cr alloy. Akagan$'e$ite is generally considered to facilitate the corrosion of steel, but our results indicate that akagan$'e$ite in the rust of Fe-Ni alloy is quantitatively different from that in rust of Fe-Cr alloy and does not facilitate the corrosion of steel. The shoulder peak observed in Cl K-XANES spectra reveals that the rust contains a chloride other than akagan$'e$ite. The energy of the shoulder peak does not correspond to that of any well-known chlorides. In the measured spectra, there is no proof that Cl, by combining with the alloying element, inhibits the alloying element from acting in corrosion resistance. The shoulder peak appears only when the content of the alloying element is lower than a certain value. This suggests that the generation of the unidentified chloride is related to the corrosion rate of steel.

Journal Articles

Cl K-edge XANES spectra of atmospheric rust on Fe, Fe-Cr and Fe-Ni alloys exposed to saline environment

Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro

Materials Transactions, 45(12), p.3356 - 3359, 2004/12

 Times Cited Count:10 Percentile:53.05(Materials Science, Multidisciplinary)

Cl K-edge XANES measurements of atmospheric corrosion products (rust) formed on Fe, Fe-Ni and Fe-Cr alloys in chloride pollution have been performed using synchrotron radiation in order to clarify roles of anticorrosive alloying elements and of Cl in the corrosion resistance of weathering steel. The spectra of binary alloys show a shoulder structure near the absorption edge. The intensity of the shoulder peak depends on the kind and amount of the alloying element, whereas the energy position is invariant. This indicates that Cl is not combined directly with alloying elements in the rust.

Journal Articles

Hardening of Fe-Cu model alloys induced by electron irradiation and neutron irradiation

Tobita, Toru; Aizawa, Kazuya; Suzuki, Masahide; Iwase, Akihiro*

Nihon Genshiryoku Gakkai Wabun Rombunshi, 3(4), p.331 - 339, 2004/12

Nevertheless, there is a possibility that $$gamma$$-ray induces embrittlement more efficiently than fast neutron, the irradiation effect of $$gamma$$-ray has not been fully clarified. Comparative experiments on irradiation hardening by 2.5MeV electron irradiation for the purpose of $$gamma$$-ray irradiation and neutron irradiation were performed to the Fe-Cu model alloys. We obtained the dose dependence and the temperature dependence on irradiation induced hardening. The growth of Cu clusters with increase in irradiation dose was confirmed by the small angle neutron scattering measurements. Although the differences in hardening between electron and neutron irradiations were very small on a displacement-per-atom (dpa) basis, the electron irradiation hardening initiated slightly earlier than the neutron. The growth of Cu clusters with increase in irradiation dose was the principal cause of hardening. The present results suggested that, from an engineering point of view, both the $$gamma$$-ray induced and neutron induced hardening can be well scaled by using dpa.

Journal Articles

Electrode reaction of the Np$$^{3+}$$/Np couple at liquid Cd and Bi electrodes in LiCl-KCl eutectic melts

Shirai, Osamu; Uozumi, Koichi*; Iwai, Takashi; Arai, Yasuo

Journal of Applied Electrochemistry, 34(3), p.323 - 330, 2004/03

 Times Cited Count:28 Percentile:52.34(Electrochemistry)

The electrode reactions of the Np$$^{3+}$$/Np couple at liquid Cd and Bi electrodes were investigated by cyclic voltammetry at 723, 773 and 823 K in LiCl-KCl eutectic melt. It was found that the diffusion of Np$$^{3+}$$ in the salt phase was a rate-determining step in the cathodic reaction when the concentration of NpCl$$_{3}$$ was less than about 1 wt.% and the liquid Cd or Bi phase was not saturated with Np. The redox potentials of the Np$$^{3+}$$/Np couple at liquid Cd electrode at 723, 773 and 823 K were observed more positively than those at Mo electrode by 0.158, 0.140 and 0.126 V, respectively. The potential shift would result from a lowering of activity of Np in Cd phase according to the alloy formation of NpCd$$_{11}$$ at 723 K and NpCd$$_{6}$$ at 773 and 823 K. The redox potentials of the Np$$^{3+}$$/Np couple at liquid Bi electrode at 723, 773 and 823 K were more positive than those at Mo electrode by 0.427, 0.419 and 0.410 V, respectively, which would be attributable to a lowering of activity of Np in Bi phase according to the formation of NpBi$$_{2}$$.

Journal Articles

Microstructural development and radiation hardening of neutron irradiated Mo-Re alloys

Nemoto, Yoshiyuki; Hasegawa, Akira*; Sato, Manabu*; Abe, Katsunori*; Hiraoka, Yutaka*

Journal of Nuclear Materials, 324(1), p.62 - 70, 2004/01

 Times Cited Count:38 Percentile:90.02(Materials Science, Multidisciplinary)

In this study, stress-relieved specimens and recrystallized specimens of pure Mo and Mo-Re alloys (Re content=2,4,5,10,13 and 41wt%) were neutron irradiated up to 20dpa at various temperatures (681-1072K). On microstructure observation, sigma phase and chi phase precipitates were observed in all irradiated Mo-Re alloys. Voids were observed in all irradiated specimen, and dislocation loops and dislocations were observed in the specimens that were irradiated at lower temperatures. On Vickers hardness testing, all of the irradiated specimens showed hardening. Especially Mo-41Re were drastically embrittled after irradiation at 874K or less. From these results, authors discuss about relation between microstructure development and radiation hardening, embrittlement, and propose the most efficient Re content and thermal treatment for Mo-Re alloys to be used under irradiation condition.

JAEA Reports

Report of the 2nd Joint Research Committee for Fusion Reactor and Materials; July 12, 2002, Tokyo, Japan

Research Committee for Fusion Reactor; Research Committee for Fusion Materials

JAERI-Review 2003-015, 123 Pages, 2003/05

JAERI-Review-2003-015.pdf:24.89MB

no abstracts in English

Journal Articles

Hardening of Fe-Cu alloys by swift heavy ion irradiation

Iwase, Akihiro; Hasegawa, Tadayuki*; Chimi, Yasuhiro; Tobita, Toru; Ishikawa, Norito; Suzuki, Masahide; Kambara, Tadashi*; Ishino, Shiori*

Nuclear Instruments and Methods in Physics Research B, 195(3-4), p.309 - 314, 2002/10

 Times Cited Count:12 Percentile:60.73(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Use of high energy ions for the mechanistic study of irradiation embrittlement in pressure vessel steels using Fe-Cu model alloys

Morita, Kenji*; Ishino, Shiori*; Tobita, Toru; Chimi, Yasuhiro; Ishikawa, Norito; Iwase, Akihiro

Journal of Nuclear Materials, 304(2-3), p.153 - 160, 2002/08

 Times Cited Count:13 Percentile:63.33(Materials Science, Multidisciplinary)

To study the mechanism of irradiation embrittlement in pressure vessel alloys, we performed high energy ion irradiation experiments using FeCu model alloys. The dependences of Vickers hardness change by irradiation on ion fluence, irradiation temperature and Cu content were discussed.

JAEA Reports

Report of Joint Research Committee for Fusion Reactor and Materials; July 16, 2001, Tokyo, Japan

Research Committee for Fusion Reactor; Research Committee for Fusion Materials

JAERI-Review 2002-008, 79 Pages, 2002/03

JAERI-Review-2002-008.pdf:9.92MB

Joint research committee for fusion reactor and materials was held in Tokyo on July 16, 2001. In the committee, a review of the development programs and the present status on the blanket technology, materials and IFMIF(International Fusion Materials Irradiation Facility) in JAERI and Japanese Universities was reported, and the direction of these R&D was discussed. Moreover, the progress of the collaboration between JAERI and Japanese Universities was discussed. This report consists of the summaries of the presentations and the viewgraphs which were used at the committee.

JAEA Reports

Study on high-performance fuel cladding materials; Joint research report in FY 1999-2000 (Phase 1) (Joint research)

Kiuchi, Kiyoshi; Ioka, Ikuo; Tachibana, Katsumi; Suzuki, Tomio; Fukaya, Kiyoshi*; Inohara, Yasuto*; Kambara, Shozo; Kuroda, Yuji*; Miyamoto, Satoshi*; Ogura, Kazutomo*

JAERI-Research 2002-008, 63 Pages, 2002/03

JAERI-Research-2002-008.pdf:7.85MB

no abstracts in English

Journal Articles

Orbital angular momentum and interpretation of core-absorption magnetic circular dichroism on the band picture in Co-based Heusler alloys Co$$_{2}Y$$Sn ($$Y$$=Ti, Zr, and Nb)

Yamasaki, Atsushi*; Imada, Shin*; Arai, Ryuji*; Utsunomiya, Hiroshi*; Suga, Shigemasa*; Muro, Takayuki*; Saito, Yuji; Kanomata, Takeshi*; Ishida, Shoji*

Physical Review B, 65(10), p.104410_1 - 104410_6, 2002/03

 Times Cited Count:60 Percentile:89.21(Materials Science, Multidisciplinary)

The magnetic circular dichroism (MCD) of core-level absorption [x-ray absorption spectroscopy (XAS)] spectra in the soft x-ray region has been measured for the ferromagnetic Heusler alloys Co$$_{2}$$TiSn, Co$$_{2}$$ZrSn, and Co$$_{2}$$NbSn. The many-peak structures which are clearly observed in the Co 2p-3d XAS-MCD spectra cannot be well explained by atomic multiplet calculations but are better explained by the Co 3d unoccupied states predicted by linear muffin-tin orbital atomic sphere approximation band structure calculations. The MCD spectra show an obvious contribution of the orbital angular momentum component to the magnetic moment in these alloys. The ratio between the orbital angular momentum and spin derived from the MCD spectra varies by more than a factor of 2 within these alloys. The mechanism of this variation is discussed in comparison with the band structure calculations.

Journal Articles

EXAFS study on local structural changes in amorphous Fe-Zr-B alloys

Nakata, Yoshiyuki*; Hara, Naoyuki*; Hirotsu, Yoshihiko*; Emura, Shuichi*; Makino, Akihiro*; Uruga, Tomoya*; Harada, Makoto*; Nishihata, Yasuo; Yoneda, Yasuhiro; Kubozono, Yoshihiro*

Japanese Journal of Applied Physics, 38(Suppl.38-1), p.404 - 407, 1999/06

The EXAFS spectra on Zr K-edge are investigated for as-formed Fe-7at%Zr-3at%B amorphous alloys and annealed ones at 693 K and 773 K for an hour in order to reveal local structural changes due to annealing. The analysis shows that the atomic distances of Fe-Zr and Zr-Zr pairs increase during annealing and approach those in a Fe3Zr or/and Fe2Zr metallic comound. The change in the atomic distances suggests that medium range ordered clusters should be formed during annealing.

63 (Records 1-20 displayed on this page)